Synthesis, characterization, and molecular structure of [(CH3)(2)C(C5H4)(2)]Fe-2(mu-CO)(2)(CO)(2) Version 4.0

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Synthesis, characterization, and molecular structure of [(CH3)(2)C(C5H4)(2)]Fe-2(mu-CO)(2)(CO)(2)
vandenBerg W, Cromsigt JAMTC, Bosman WP, Smits JMM, deGelder R, Gal AW, Heck J
JOURNAL OF ORGANOMETALLIC CHEMISTRY 524: (1-2) 281-284 NOV 1 1996

Document type: Article

Language: English

Cited References: 20

Times Cited: 2

Abstract:
[(CH3)(2)C(C5H4)(2)]Fe-2(mu-CO)(2)(CO)(2) (1) has been synthesized from 2,2-dicyclopentadienyl propane and pentacarbonyliron in 26% yield. The crystal and molecular structure of 1 has been determined by X-ray diffraction. The molecule has the expected carbonyl-bridged structure with a cis configuration of the cyclopentadienyl rings. The Fe-Fe distance of 2.484 Angstrom is the shortest one reported to date for ring-bridged dicyclopentadienyl di-iron tetracarbonyl complexes.

Author Keywords:
carbon monoxide, cyclopentadienyl, iron, nuclear magnetic resonance, X-ray diffraction

KeyWords Plus:
COMPLEXES, CHEMISTRY, CRYSTAL

Addresses:
UNIV HAMBURG, INST ANORGAN & ANGEW CHEM, D-20146 HAMBURG, GERMANY.
CATHOLIC UNIV NIJMEGEN, NIJMEGEN SON RES CTR, DEPT INORGAN CHEM, NL-6525 ED NIJMEGEN, NETHERLANDS.

Publisher:
ELSEVIER SCIENCE SA LAUSANNE, LAUSANNE

IDS Number:
VZ152

ISSN:
0022-328X

Article 28 of 38