Molecular structure and absolute configuration of (-)-(1R,2S,6R,7S,2 ' S)-5-(2 '-hydroxymethylpyrrolidin-l '-yl)-endo-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one Version 4.0

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Molecular structure and absolute configuration of (-)-(1R,2S,6R,7S,2 ' S)-5-(2 '-hydroxymethylpyrrolidin-l '-yl)-endo-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one
de Gelder R, Smits JMM, Ramesh NG, Bakkeren FJAD, Klunder AJH
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 28: (6) 493-495 JUN 1998

Document type: Article

Language: English

Cited References: 11

Times Cited: 0

Abstract:
The crystal and molecular structure of(-)-(1R,2S,6R,7S,2'S)-5-(2'-hydroxymethyl-pyrrolidin-1'-yl)-endo-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one is described. Knowing the absolute configuration of the prolinol moiety (S) the X-ray diffraction study established the absolute configuration of the title compound. The structure was refined to R-1 = 0.0322 for 1237 reflections (with I greater-than 2 sigma(I)). Crystal data: C15H19NO2, monoclinic, space group P2(1), a = 6.0757(4), b = 11.3473(5), c = 9.5114(7)Angstrom, beta = 104.686(6)degrees, V = 634.32(7) Angstrom(3), and Z = 2.

Author Keywords:
crystal structure, tricyclodecadienone, enaminone, dynamic kinetic resolution

KeyWords Plus:
DIELS-ALDER REACTION, ROUTE

Addresses:
de Gelder R, Univ Nijmegen, Dept Inorgan Chem, Nijmegen SON Res Ctr, Toernooiveld 1, NL-6525 ED Nijmegen, Netherlands.
Univ Nijmegen, Dept Inorgan Chem, Nijmegen SON Res Ctr, NL-6525 ED Nijmegen, Netherlands.
Univ Nijmegen, Dept Organ Chem, Nijmegen SON Res Ctr, NL-6525 ED Nijmegen, Netherlands.

Publisher:
PLENUM PUBL CORP, NEW YORK

IDS Number:
127ZQ

ISSN:
1074-1542

Article 13 of 38