A stable three-coordinate rhodium(I) olefin complex Version 4.0

General Search Results--Full Record

Article 12 of 38

A stable three-coordinate rhodium(I) olefin complex
Budzelaar PHM, de Gelder R, Gal AW
ORGANOMETALLICS 17: (19) 4121-4123 SEP 14 1998

Document type: Article

Language: English

Cited References: 23

Times Cited: 3

Abstract:
Reaction of LLi (L = ArNC(Me)CHC(Me)NAr, Ar = 2,6-Me2C6-H-3) with [Rh(COE)(2)Cl](2) (COE = cyclooctene) produces stable, three coordinate LRh(COE) (1). At room temperature in solution, the LRh, fragment moves rapidly over one face of the COE ligand via reversible allyl hydride formation.

KeyWords Plus:
NUMERICAL-INTEGRATION, BOND, ENERGIES

Addresses:
Budzelaar PHM, Catholic Univ Nijmegen, Dept Inorgan Chem, Toernooiveld 1, NL-6525 ED Nijmegen, Netherlands.
Catholic Univ Nijmegen, Dept Inorgan Chem, NL-6525 ED Nijmegen, Netherlands.

Publisher:
AMER CHEMICAL SOC, WASHINGTON

IDS Number:
125BK

ISSN:
0276-7333

Article 12 of 38