Synthesis and reactions of some derivatives of (3,6S,9R,10R,11S)-1,4,7-trioxaspiro[5,5]undecane-3,9,10,11-tetrol: novel quasi-saccharides Version 4.0

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Synthesis and reactions of some derivatives of (3,6S,9R,10R,11S)-1,4,7-trioxaspiro[5,5]undecane-3,9,10,11-tetrol: novel quasi-saccharides
Regeling H, Sunghwa F, Zwanenburg B, de Gelder R, Chittenden GJF
CARBOHYDRATE POLYMERS 37: (3) 323-333 NOV 1998

Document type: Article

Language: English

Cited References: 20

Times Cited: 0

Abstract:
The title compound was obtained by reductive ozonolysis of allyl beta-D-fructopyranoside. The synthesis and characterization of a number of C-3-substituted derivatives using conventional carbohydrate procedures is described. Some of the products may be of biological interest as carbohydrate mimics. The structures of two of the basic products (8 and 9) were substantiated by X-ray diffraction studies. (C) 1998 Elsevier Science Ltd. All rights reserved.

Author Keywords:
spiro-fructosides-quasisaccharides, carbohydrate mimics, X-ray diffraction

KeyWords Plus:
ACTIVATION, CLEAVAGE, ALLYL

Addresses:
Chittenden GJF, Catholic Univ Nijmegen, NSR Ctr, Dept Organ Chem, Toernooiveld, NL-6525 ED Nijmegen, Netherlands.
Catholic Univ Nijmegen, NSR Ctr, Dept Organ Chem, NL-6525 ED Nijmegen, Netherlands.

Publisher:
ELSEVIER SCI LTD, OXFORD

IDS Number:
148HQ

ISSN:
0144-8617

Article 11 of 38